Understanding Clay and Glaze Materials: You Don't Have to Be a Super Genius
You Don't Have to Be a Super Genius to Understand Glaze and Clay Materials.
Ceramic Arts Network
Today, we live in an age of super abundance of ceramic raw materials. Innumerable clays and glaze materials offer us a bewildering array of choices. Far from understanding glazes and these materials as familiar rocks, feldspars, and clays, each with unique personalities, we know them only as white, gray, or brown powders neatly packaged in uniform bags.
But we all know that getting to know them better can only improve our work. Happy learning! - Jennifer Poellot Harnetty, editor
There are probably as many kinds of clay as there are riverbanks, creekbeds, roadcuts, abandoned coal mines and backyard gullies, but most of the clays that many of us use on a regular basis are commercially mined.
Because not all materials are available through all suppliers, this chart is meant to provide data for the most common clays used in recipes you are likely to come across. You can use these data to compare the materials available through your supplier,
or those you have on hand, with materials in the published recipes.
While the satisfaction, discovery and personal control that is possible through prospecting and processing your own clay are certainly valid reasons for the effort, most of us rely on the consistency and (relative) reliability of materials mined in large quantities. Even though the reasons for using commercially mined clays are most often based on a desire for a trouble-free product, the properties of clay as a natural material
can make this goal somewhat elusive.
The following chart contains recent information, however, because the chemical and physical makeup of naturally mined materials can change across a given deposit, this chart is meant to be used as a starting point for clay substitutions. In order to precisely recalculate a recipe using a substituted clay, you will need to obtain a current data sheet for all materials you purchase from your supplier.
Please note that the clays are presented in alphabetical order, and the formulae are presented with alumina (Al2O3) in unity (totaling 1). This makes it easier to immediately see the ratio of alumina to silica, and also more accurately compares the
relative amounts of all other components in the clays.
Unity Molecular Formulas of Clay Materials
Primary Function of Common Ceramic Raw Materials
Material
Glaze Function
Substitute
Comment
Barium Carbonate
Flux
Strontium carbonate
Bentonite
Suspension agent
Ball Clay
Do not exceed 3%
Bone Ash
Opacifier
Borax
Flux, glassmaker
Boron frits
Chrome Oxide
Colorant
Green
Cobalt Carbonate
Colorant
Cobalt oxide
Blue
Copper Carbonate
Colorant
Copper oxide
Greens, copper reds
Cornwall Stone
Flux, opacifier
Custer Feldspar
Glaze core
Potash feldspar (G-200)
Dolomite
Flux, opacifier
Whiting
Many brands
EPK Kaolin
Alumina, opacity
Kaolin
Ferro Frit 3110
Glaze core, flux
Pemco P-IV05, Fusion F-75
Crystalline glazes
Ferro Frit 3124
Glaze core, flux
F-19, P-311, Hommel 90
Boron frit
Ferro Frit 3134
Glaze core, flux
F-12, P-54, Hommel 14
Boron frit
Ferro Frit 3195
Glaze core, flux
Hommel 90, Fusion F-2
Complete glaze
Ferro Frit 3269
Flux, glaze core
Pemco P-25
Ferro Frit 3278
Flux, glaze core
Fusion F-60, Pemco P-830
G-200 Feldspar
Glaze core
Potash feldspar (Custer)
Green Nickel Oxide
Colorant
Black nickel oxide
Blues, tan, browns, greens, grays
Kentucky OM4 Ball Clay
Alumina, opacity
Ball Clay
Kona F-4 Feldspar
Glaze core
Soda feldspar
Lithium Carbonate
Flux
Magnesium Carbonate
Flux, opacifier
Promotes crawling
Manganese Dioxide
Colorant
Purple, red, yellow-brown
Nepheline Syenite
Glaze core
Red Iron Oxide
Colorant
Celadon green to brown
Rutile
Colorant
Ilmenite
Silica
Glass former, glaze fit
Flint
Use 325 mesh
Spodumene
Lithium glaze core
Strontium Carbonate
Flux
Barium carbonate
Talc
Flux, opacifier
Many brands
Tin Oxide
Opacifier
Zircopax
Titanium Dioxide
Opacifier
Whiting
Flux, opacifier
Wollastonite, Dolomite
Many brands
Wollastonite
Flux, opacifier
Whiting, dolomite
Wood Ash
Glaze core, flux, colorant
Whiting
Results vary by type
Zinc Oxide
Flux, opacifier
Zircopax
Opacifier
Superpax, Ultrox
Notes
1. Substituting glaze ingredients may alter color, texture, opacity, viscosity, and/or sheen, as well as create pinholing, crazing, black spotting, and/or pitting. In most cases, additional adjustments to other ingredients
need to occur when substituting.
2. Test and record your results.
3. Materials vary from supplier to supplier and batch to batch.
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Published Dec 20, 2018
Today, we live in an age of super abundance of ceramic raw materials. Innumerable clays and glaze materials offer us a bewildering array of choices. Far from understanding glazes and these materials as familiar rocks, feldspars, and clays, each with unique personalities, we know them only as white, gray, or brown powders neatly packaged in uniform bags.
But we all know that getting to know them better can only improve our work. Happy learning! - Jennifer Poellot Harnetty, editor
Because not all materials are available through all suppliers, this chart is meant to provide data for the most common clays used in recipes you are likely to come across. You can use these data to compare the materials available through your supplier, or those you have on hand, with materials in the published recipes.
While the satisfaction, discovery and personal control that is possible through prospecting and processing your own clay are certainly valid reasons for the effort, most of us rely on the consistency and (relative) reliability of materials mined in large quantities. Even though the reasons for using commercially mined clays are most often based on a desire for a trouble-free product, the properties of clay as a natural material can make this goal somewhat elusive.
The following chart contains recent information, however, because the chemical and physical makeup of naturally mined materials can change across a given deposit, this chart is meant to be used as a starting point for clay substitutions. In order to precisely recalculate a recipe using a substituted clay, you will need to obtain a current data sheet for all materials you purchase from your supplier.
Please note that the clays are presented in alphabetical order, and the formulae are presented with alumina (Al2O3) in unity (totaling 1). This makes it easier to immediately see the ratio of alumina to silica, and also more accurately compares the relative amounts of all other components in the clays.
Unity Molecular Formulas of Clay Materials
Primary Function of Common Ceramic Raw Materials
Notes
1. Substituting glaze ingredients may alter color, texture, opacity, viscosity, and/or sheen, as well as create pinholing, crazing, black spotting, and/or pitting. In most cases, additional adjustments to other ingredients need to occur when substituting.
3. Materials vary from supplier to supplier and batch to batch.
**First published in 2010
Unfamiliar with any terms in this article? Browse our glossary of pottery terms!
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